May 17, 2020

Desalination Plant to Employ Energy Recovery

Admin
5 min
Carlsbad desalination plant construction
With the sun low in the horizon over the Pacific Ocean and the sky slowly turning from Capri blue to blood orange, surfers try to catch one last wave a...

With the sun low in the horizon over the Pacific Ocean and the sky slowly turning from Capri blue to blood orange, surfers try to catch one last wave as families fold up their chairs and shake out their towels on the beach in Carlsbad, Calif.  Behind them in the distance the dingy gray smokestack of the Encina Power Plant juts upward as gangly construction cranes sway in the background. 

The cranes are there working on the new Carlsbad Desalination Plant, which when it opens in 2016, will bring the largest, most technologically advanced, and energy-efficient desalination plant in the western hemisphere to Southern California. The project will include energy recovery devices, an advanced pumping system, and cutting edge reverse osmosis membranes. 

“We are using the most current state-of-the-art evolution of those technologies, but still have it commercially tested and highly reliable,” says Jonathan Loveland, PE, vice president, Technical Services for Poseidon Water, the developer of the plant.

The plant, a $1 billion project 12 years in the making, will produce 50 million gallons per day of treated water, which could serve up to 112,000 households in northern San Diego County. The area, which is semi-arid and relies on water pumped in from rivers and lakes in Northern California and Colorado, will finally have a locally-controlled, drought-proof supply of water that meets all state and federal drinking water standards.

In November 2012 the San Diego County Water Authority signed a 30 year water purchase agreement to buy the 50 million gallons per day of water from the Carlsbad Desalination Plant. Poseidon Water then agreed to build a 10 mile pipeline to the Twin Oaks Valley treatment facility in San Marcos that feeds into the county water system.  

Plant Technology

The worksite is adjacent to the 60 year old Encina Power Plant and sits on the Agua Hedionda Lagoon, a few hundred yards from the Pacific Ocean. After removing old industrial equipment and some hazardous material from the site, construction began in earnest this spring.

But before the first pipe was laid, concrete pad poured, or water tank was constructed, Poseidon Water made sure the latest technology in seawater filters, pumps, and energy recovery would be implemented into the desalination plant.

“Seawater desalination employs some of the same technologies used for surface water treatment throughout the U.S. and world,” Loveland says. “Seawater desalination involves taking a high pressure reverse osmosis system and dropping it in the middle of a surface water treatment plant.”

The technology Poseidon is using for salt removal is spiral wound reverse osmosis membrane. The membranes are eight inches in diameter and 40 inches long and there will be 15,000 of them in the plant to remove the salt from the seawater.

It’s more of a molecular separation process than a traditional filter. There are pores in the membrane that allow water to move through the membrane faster than salt molecules. In the end of the process, one side of the membrane has concentrated salt and on the other side is relatively pure water.

“It is filtering but it is doing it on a much different level than pretreatment filters can,” Loveland says. “It’s really a separation process by which you remove the salt.”

To push the seawater through the reverse osmosis membranes a unique pumping system, called a pressure center design, will be used. The pumps feeding the 14 RO trains have 8,000 horsepower motors attached and a unique configuration that offers energy savings.

“Basically, we have large constant speed reverse osmosis pumps, because to perform RO on seawater, we need to pressurize the system to somewhere between 800 to 900 psi,” Loveland says. “These are some of the largest pumps of their kind; you would only get larger pumps on water distribution systems like on the aqueducts in California.”

 When water is pressured to 900 psi to move through the membranes, a lot of that energy is left over. Those energy leftovers will be captured and transferred back to the front of the system. The PX Pressure Exchanger Q300 unites, provided by Energy Recovery Inc., consume no electrical power and recycle lost energy in the form of pressure with 98 percent efficiency. 

“At 50 million gallons per day, we chose the most reliable and efficient energy recovery technology on the market,” says Avshalom Felber, CEO of IDE Technologies, the contractor of the project, which awarded Energy Recovery the contract for its ERDs. “For larger plants such as the Carlsbad Desalination Project, it's important to weigh the energy saving solutions and economies of scale.”

By using the energy recovery devices, the plant should save an estimated 116 million kilowatt-hours of energy per year, the equivalent of $12 million. This energy savings will also reduce CO2 emissions by 41,000metric tons per year – roughly the annual greenhouse gas emissions from 8,542 passenger vehicles.

“The Carlsbad project has moved the needle for the desalination industry in the U.S.," says Tom Rooney, CEO at Energy Recovery. “We're excited to bring our experience and technologies to help this project and future U.S. desalination plants.”

Water Partner

The Encina Power Plant pumps about 800,000 million gallons of water per day through its condenser and to cool its boilers. After the water leaves the power plant the desalination plant will siphon off 100 million gallons per day to produce 50 million gallons of water daily.

The left over 50 million gallons is pumped out of the desalination plant and diluted with the 700,000 million gallons that the power plant is pumping back out into the ocean.

“There's a lot of dilution that takes place before that water goes back into the ocean and that's done to minimize salinity impact on marine life,” Loveland says. “I wouldn't say it's usual to do it that way – there are facilities around the world where they don't do that – but the environmental stewardship of the coastal area is important to us.”

Once built, the desalination plant will help to preserve the 400-acre Agua Hedionda Lagoon and the surrounding watershed. Onsite improvements will include an intake pump station, and pipeline, concentrate return pipeline, sewer connection; electrical transmission lines, road improvements, and product water pump station and pipeline.

In addition, the Carlsbad desalination plant is signaling a trend for upcoming projects in the U.S. According to Global Water Intelligence, there are currently more than 12 desalination projects in various stages of planning in California, including one in Huntington Beach, and more than 40 medium and large projects on the drawing board across North America.

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Oct 19, 2020

Itronics successfully tests manganese recovery process

cleantech
manganese
USA
Scott Birch
3 min
Nevada firm aims to become the primary manganese producer in the United States
Nevada firm aims to become the primary manganese producer in the United States...

Itronics - a Nevada-based emerging cleantech materials growth company that manufacturers fertilisers and produces silver - has successfully tested two proprietary processes that recover manganese, with one process recovering manganese, potassium and zinc from paste produced by processing non-rechargeable alkaline batteries. The second recovers manganese via the company’s Rock Kleen Technology.

Manganese, one of the four most important industrial metals and widely used by the steel industry, has been designated by the US Federal Government as a "critical mineral." It is a major component of non-rechargeable alkaline batteries, one of the largest battery categories sold globally.

The use of manganese in EV batteries is increasing as EV battery technology is shifting to use of more nickel and manganese in battery formulations. But according to the US Department of Interior, there is no mine production of manganese in the United States. As such, Itronics is using its Rock Kleen Technology to test metal recoverability from mine tailings obtained from a former silver mine in western Nevada that has a high manganese content. 

In a statement, Itronics says that its Rock Kleen process recovers silver, manganese, zinc, copper, lead and nickel. The company says that it has calculated – based on laboratory test results – that if a Rock Kleen tailings process is put into commercial production, the former mine site would become the only primary manganese producer in the United States.

Itronics adds that it has also tested non-rechargeable alkaline battery paste recovered by a large domestic battery recycling company to determine if it could use one of its hydrometallurgical processes to solubilize the manganese, potassium, and zinc contained in the paste. This testing was successful, and Itronics was able to produce material useable in two of its fertilisers, it says.

"We believe that the chemistry of the two recovery processes would lend itself to electrochemical recovery of the manganese, zinc, and other metals. At this time electrochemical recovery has been tested for zinc and copper,” says Dr John Whitney, Itronics president. 

“Itronics has been reviewing procedures for electrochemical recovery of manganese and plans to move this technology forward when it is appropriate to do so and has acquired electro-winning equipment needed to do that.

"Because of the two described proprietary technologies, Itronics is positioned to become a domestic manganese producer on a large scale to satisfy domestic demand. The actual manganese products have not yet been defined, except for use in the Company's GOLD'n GRO Multi-Nutrient Fertilisers. However, the Company believes that it will be able to produce chemical manganese products as well as electrochemical products," he adds.

Itronics’ research and development plant is located in Reno, about 40 miles west of the Tesla giga-factory. Its planned cleantech materials campus, which will be located approximately 40 miles south of the Tesla factory, would be the location where the manganese products would be produced.

Panasonic is operating one of the world's largest EV battery factories at the Tesla location. However, Tesla and other companies have announced that EV battery technology is shifting to use of nickel-manganese batteries. Itronics is positioned and located to become a Nevada-0based supplier of manganese products for battery manufacturing as its manganese recovery technologies are advanced, the company states.

A long-term objective for Itronics is to become a leading producer of high purity metals, including the U.S. critical metals manganese and tin, using the Company's breakthrough hydrometallurgy, pyrometallurgy, and electrochemical technologies. ‘Additionally, Itronics is strategically positioned with its portfolio of "Zero Waste Energy Saving Technologies" to help solve the recently declared emergency need for domestic production of Critical Minerals from materials located at mine sites,’ the statement continues.

The Company's growth forecast centers upon its 10-year business plan designed to integrate its Zero Waste Energy Saving Technologies and to grow annual sales from $2 million in 2019, to $113 million in 2025.

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